Advanced boron-doped carbon papers with excellent electrical conductivity and low graphitization temperature for PEM fuel cells

• Published in: International journal of hydrogen energy Vol. 50; pp. 1279 - 1293
• Main Authors: Shao, Qinsi, Wang, Shuli, Yuan, Ming, Wang, Hao, Jung, Joey Chung-Yen, Zhang, Jiujun
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 02.01.2024
• Subjects: Boron; Carbon paper; Catalytic graphitization; Fuel cell; Gas diffusion layer; Boron; Gas diffusion layer; Catalytic graphitization; Carbon paper; Fuel cell
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2023.06.261

A facile method is proposed in this work to prepare a carbon paper (CP) with outstanding properties by doping boron to catalyze graphitization at lower temperature. Boron was introduced into CP by impregnating carbon fiber preform into a boron/phenolic resin/ethanol solution, and then CP was obtained after the consecutive procedures of hot pressing, carbonization, and graphitization. Morphology, microstructure, composition, and physical properties of the doped and undoped CPs were thoroughly investigated via various techniques to exam the effects of boron concentration and graphitization temperature. Furthermore, the boron doped CP was fabricated into fuel cell gas diffusion layer (GDL) and membrane electrode assembly (MEA) to evaluate its performance through the single cell performance. The findings indicated CP doping with 2 wt% boron could lower the graphitization temperature by at least 200 °C. The B-doped GDL had a higher power density in comparison with the undoped GDLs made in our lab or from the commercial brands. •The innovative preparation method for carbon paper with high conductivity.•The effect of boron concentration and graphitization temperature on carbon paper.•The single cell performance of B-doped gas diffusion layer.