Rational introduction of S and P in multi-stage electrocatalyst to drive a large-current-density water oxidation reaction and overall water splitting

• Published in: Journal of power sources Vol. 518; p. 230757
• Main Authors: Zhang, Yijie, Liu, Leran, Wang, Jinwei, Yao, Rui, Wu, Yun, Wang, Muheng, Zhao, Qiang, Li, Jinping, Liu, Guang
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15.01.2022
• Subjects: Heteroatom doping; Heterostructure; Large-current-density; Oxygen evolution reaction; Water splitting; Heterostructure; Water splitting; Oxygen evolution reaction; Heteroatom doping; Large-current-density
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2021.230757

Rational design and construction of electrocatalysts that can work well at large current densities are imperative for water splitting. Herein, a multi-stage P–Ni3S2/NiFe/NF electrocatalyst was rationally designed by introducing heteroatoms (S and P) and heterostructure construction. Benefitting from the optimized electronic structure configuration by the synergistic incorporation of S and P, the as-prepared P–Ni3S2/NiFe/NF electrocatalyst exhibits remarkable activity and stability towards oxygen evolution reaction (OER) in alkaline media, yielding ultralow overpotentials of 250 mV and 372 mV at the current densities of 100 mA/cm2 and 1000 mA/cm2, respectively. Moreover, its multi-stage heterostructure also endows the electrocatalyst with unique multifunctional properties, making it can realize overall water splitting under a low cell voltage of 1.57 V at 10 mA/cm2, and has long-term stability. This work demonstrates the importance of rational introduction of heteroatoms and interface/surface engineering for advanced electrocatalytic materials. [Display omitted] •P–Ni3S2/NiFe/NF electrocatalyst was rationally designed and synthesized.•P–Ni3S2/NiFe/NF has stable and remarkable behaviors for water splitting.•P–Ni3S2/NiFe/NF can steadily output 1000 mA/cm2 at a overpotential of 372 mV.