The self-regulated infrared emissivity properties of BCG/MgCl2/PEG-g-CDA powders for tunable IR signals

• Published in: Infrared physics & technology Vol. 94; pp. 280 - 285
• Main Authors: Bu, Honghan, Xu, Guoyue, Liu, Chuyang, Guo, Tengchao, Tan, Shujuan
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.11.2018
• Subjects: BCG/MgCl2/PEG-g-CDA; Energy gap; Infrared emissivity; Resistivity; BCG/MgCl2/PEG-g-CDA; Energy gap; Infrared emissivity; Resistivity
• ISSN: 1350-4495; 1879-0275
• DOI: 10.1016/j.infrared.2018.09.032

•BCG/MgCl2/PEG-g-CDA powders with the self-regulation emissivity properties were synthesized.•BCG/MgCl2/PEG-g-CDA powders can change the infrared emissivity values from 0.55 to 0.95 at the temperature range of 50–65 °C.•The mechanism for the tunable emissivity properties are fully revealed.•BCG/MgCl2/PEG-g-CDA powder is a potential candidate for changing the IR signal of aerial vehicles. The green BCG/MgCl2/PEG-g-CDA powders were synthesized at different temperatures via liquid-phase reaction method. The microstructures of the synthesized powders were analyzed and characterized by FT-IR, XRD and ChemDraw software. The effects of synthesized temperatures on infrared emissivity properties of the powders in the wavelength range 3–5 μm were investigated systematically. It is found that the powders heated at 100 °C exhibit the optimum crystallinity at room temperature and thus show the largest variation (0.4) in infrared emissivity with the test temperature varying from 50 °C to 65 °C. Furthermore, the mechanisms for the self-regulated infrared emissivity properties are also explored thoroughly. The variation of infrared emissivity with temperature is ascribed to the changes in resistivity, which is induced by the transformation of PEG-g-CDA between crystalline and amorphous as well as the molecular structure transition of BCG between quinone and lactone. Our results suggest that BCG/MgCl2/PEG-g-CDA powders are potential candidates for intelligent infrared camouflage.