Low carbon ultrasonic production of alternate fuel: Operational and mechanistic concerns of the sonochemical process of hydrogen generation under various scenarios

• Published in: International journal of hydrogen energy Vol. 46; no. 53; pp. 26770 - 26787
• Main Authors: Kerboua, Kaouther, Hamdaoui, Oualid, Islam, Md Hujjatul, Alghyamah, Abdulaziz, Hansen, Henrik Erring, Pollet, Bruno G.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 03.08.2021
• Subjects: Acoustic frequency; Acoustic pressure; Hydrogen; Metrics; Saturating gas; Sonochemistry; Saturating gas; Metrics; Sonochemistry; Hydrogen; Acoustic frequency; Acoustic pressure
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2021.05.191

Sonochemistry is considered as one of the cleaner pathways for hydrogen production. The present paper investigates the potential of this technique based upon mass, mass to energy and energy conversion metrics, using modelling and experimental approaches. Four scenarios are examined assuming four saturating gases, namely O2, air, N2 and Ar, four acoustic frequencies, i.e., 20, 210, 326 and 488 kHz, and considering common acoustic intensities then common net electric power. The study revealed that Ar is the best fitting saturating gas for the sonochemical production of hydrogen. With a common acoustic intensity of 0.48 W/cm2, an optimum ratio of H2 molar yield to acoustic energy intensity is retrieved at 210 kHz, while with a common net electric power of 87 W, the highest ratio of hydrogen yield to electric energy was observed at 20 kHz. Results were interpreted based upon emitter surface, energy conversion and distinction of calorimetric and cavitational energies. •Sono-H2 is examined through mass, mass to energy and energy conversion metrics.•Ar is the best fitting saturating gas for the sonochemical production of hydrogen.•At 0.48 W/cm2, the optimal frequency for H2 yield to acoustic intensity is 210 kHz.•At 87 We, the highest ratio for H2 yield to electric energy is observed at 20 kHz.•The optimal frequency for electric to acoustic energy conversion is 20 kHz.