The identification of specific N-configuration responsible for Li-ion storage in N-doped porous carbon nanofibers: An ex-situ study

• Published in: Journal of power sources Vol. 483; p. 229174
• Main Authors: Samdani, Jitendra Shashikant, Tran, Thanh-Nhan, Kang, Tong-Hyun, Lee, Byong-June, Jang, Yun Hee, Yu, Jong-Sung, Shanmugam, Sangaraju
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 31.01.2021
• Subjects: Free-standing electrode; Li-ion battery; N-configurations; N-doped porous carbon nanofibers; Pyridinic-N; N-doped porous carbon nanofibers; N-configurations; Pyridinic-N; Li-ion battery; Free-standing electrode
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2020.229174

Nitrogen (N)-doped carbon is widely used as an anode material for Li-ion battery (LIB). However, the identification of a specific type of N-configuration responsible for Li-ion storage in N-doped carbon is an elusive topic for LIB. Herein, the N-doped porous carbon nanofibers (N-pCNFs) with various atomic percentages of N and different types of N-configurations are prepared by carbonization of polyacrylonitrile-Zeolitic imidazolate framework-8 fibres at 800, 900, and 1000 °C in N2 atmosphere. The N content of pCNFs-800, N-pCNFs-900, and N-pCNFs-1000 samples are found to be 12.9, 9.4, and 4.8% atomic percentage, respectively. The free-standing/binder-free N-pCNFs-800, N-pCNFs-900, and N-pCNFs-1000 anode electrodes deliver the reversible Li storage capacity of 650, 805, and 520 mAh g−1, respectively at 0.1 C-rate. The ex-situ X-ray diffraction, scanning electron, and transmission electron microscopic results of N-pCNFs-900 indicate the formation of the solid electrolyte interface (SEI) layer. Further, the ex-situ X-ray photoelectron spectroscopy (XPS) analysis of N-pCNFs-900 identifies the presence of LiF, LixPF5-x, LixPOF5-x, Li-O-C, and R-COOLi constituents of the SEI layer and the deconvoluted XPS N1s spectra confirms that the pyridinic-N is responsible for Li-ion storage sites in N-pCNFs. [Display omitted] •N-pCNF with varying atomic percentage of pyridinic-N is successfully synthesized.•N-pCNF is tested as a free-standing and binder-free anode electrode for Li-ion battery.•N-pCNF-900 shows the highest reversible Li-ion storage capacity.•Pyridinic-N is beneficial for Li-ion storage in N-pCNF.