Perfluorocyclobutyl-based methacrylate monomers: Synthesis and radical polymerization

A new class of methacrylate monomers containing perfluorocyclobutyl unit was synthesized in multi-steps including crossing-dimerization, demethylation and esterification using commercially available p-substituted phenol, tetrafluoroethylene and methacryloyl chloride as starting materials. These mono...

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Bibliographic Details
Published inJournal of fluorine chemistry Vol. 130; no. 3; pp. 354 - 360
Main Authors Li, Yongjun, Zhang, Sen, Tong, Liang, Li, Qingnuan, Li, Wenxin, Lu, Guolin, Liu, Hao, Huang, Xiaoyu
Format Journal Article
LanguageEnglish
Published LAUSANNE Elsevier B.V 01.03.2009
Elsevier
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Crossing-dimerization
Methacrylate
Perfluorocyclobutyl (PFCB)
Physical Sciences
Science & Technology
Crossing-dimerization
Methacrylate
Perfluorocyclobutyl (PFCB)
ETHER POLYMERS
ABA TRIBLOCK COPOLYMER
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Summary:A new class of methacrylate monomers containing perfluorocyclobutyl unit was synthesized in multi-steps including crossing-dimerization, demethylation and esterification using commercially available p-substituted phenol, tetrafluoroethylene and methacryloyl chloride as starting materials. These monomers can be polymerized in solution to provide perfluorocyclobutyl-based polymethacrylate, a kind of potential transparent material. A new class of methacrylate monomers containing perfluorocyclobutyl unit was synthesized in multi-steps including crossing-dimerization, demethylation and esterification. These monomers can be polymerized in solution to provide perfluorocyclobutyl-based polymethacrylate, a kind of potential transparent material.
ISSN:0022-1139
1873-3328
DOI:10.1016/j.jfluchem.2008.12.012