Synthesis of Au/UiO-66-NH2/Graphene composites as efficient visible-light photocatalysts to convert CO2

• Published in: International journal of hydrogen energy Vol. 46; no. 21; pp. 11621 - 11635
• Main Authors: Wang, Xiaojun, Su, Yaqiong, Yang, Guorui, Chai, Guodong, Xu, Zhicheng, Nasir, Muhammad Salman, Zheng, Xing, Wang, Caiyun, Yan, Wei
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 23.03.2021
• Subjects: Au nanoparticles; CO2 reduction; Graphene; HCOOH; Photocatalysts; UiO-66-NH2; UiO-66-NH2; Au nanoparticles; HCOOH; CO2 reduction; Graphene; Photocatalysts
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2021.01.024

The production of new solar fuel through CO2 photocatalytic reduction has aroused tremendous attention in recent years because of the increased demand of global energy sources and global warming caused by the mass concentration of CO2 in the earth's atmosphere. In this work, UiO-66-NH2 was co-modified by the Au nanoparticles (Au-NPs) and Graphene (GR). The resultant nanocomposite exhibits a strong absorption edge in visible light owing to the surface plasmon resonance (SPR) of Au-NPs. More attractively, Au/UiO-66-NH2/GR displays much higher photocatalytic activity (49.9 μmol) and selectivity (80.9%) than that of UiO-66-NH2/GR (selectivity: 71.6%) and pure UiO-66-NH2 (selectivity: 38.3%) for the CO2 reduction under visible light. The enhanced photocatalytic performance is primarily dued to the surface plasmon resonance (SPR) of Au-NPs, which could enhance the visible light absorption. The GR sheets could play as an electron acceptor with superior conductivity and thus suppress the recombination of electrons and holes. Besides, the GR could also improve the dispersibility of UiO-66-NH2 so as to expose more active sites and strengthen the capture of CO2. The contact effect and synergy effect among different samples are strengthened in the ternary composites and the photocatalytic performance is therefore improved. This study demonstrates a MOF based hybrid composite for efficient photocatalytic CO2 reduction, the findings not only prove great potential for the design and application of MOFs-based materials but also bring light to novel chances in the development of new high performance photocatalysts. [Display omitted] •Synergy of Au/UiO-66-NH2/GR nanocomposite in photocatalytic CO2 reduction.•Au-NPs enhanced the light absorption due to its surface plasmon resonance effect.•Graphene suppressed the recombination of photogenerate e−/h+ pairs.•Heterostructures accelerate the photocatalytic CO2 reduction reaction rate.•The possible reduction mechanism of the nanocomposites was discussed.