Total synthesis of (S)-espicufolin and absolute structure determinaton of espicufolin

l(S)-Espicufolin was synthesized from 1,4-dimethoxybenzene in 16 steps via an intramolecular acyl-transfer reaction as the key step; the absolute stereochemistry at the 14-position of natural espicufolin was determined to be R.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 11; pp. 1005 - 1006
Main Authors Uno, H, Sakamoto, K, Honda, E, Ono, N
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 1999
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
STROKE
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Summary:l(S)-Espicufolin was synthesized from 1,4-dimethoxybenzene in 16 steps via an intramolecular acyl-transfer reaction as the key step; the absolute stereochemistry at the 14-position of natural espicufolin was determined to be R.
ISSN:1359-7345
1364-548X
DOI:10.1039/a901602c