Highly enantioselective synthesis of dialkyl and alkyl aryl N-tosylsulfimides

Enantiomerically pure S-alkyl-S-[(4S)-4-benzyl -2-oxo-1,3-oxazolidin-3-yl]-N-tosylsulfimides react with Grignard reagents affording dialkyl and alkyl aryl sulfimides in high chemical yield and enantiomeric excess.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 6; pp. 701 - 702
Main Authors Celentano, G, Colonna, S, Gaggero, N, Richelmi, C
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 1998
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
SULFIMIDES
ASYMMETRIC-SYNTHESIS
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Summary:Enantiomerically pure S-alkyl-S-[(4S)-4-benzyl -2-oxo-1,3-oxazolidin-3-yl]-N-tosylsulfimides react with Grignard reagents affording dialkyl and alkyl aryl sulfimides in high chemical yield and enantiomeric excess.
ISSN:1359-7345
1364-548X
DOI:10.1039/a708977e