Double Mizoroki–Heck Arylation of Terminal Alkenes in the Presence of “Ligand-Free” Palladium Catalytic Systems

One-pot sequential double arylation of terminal alkenes with aryl halides to give trisubstituted derivatives is reported. The proposed approach is more advantageous than the known methods due to the use of a combination of low reactive but available aryl bromides or aryl chlorides and palladium-base...

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Bibliographic Details
Published inRussian journal of organic chemistry Vol. 59; no. 10; pp. 1704 - 1708
Main Authors Kurokhtina, A. A., Larina, E. V., Lagoda, N. A., Grigoryeva, T. A., Schmidt, A. F.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.10.2023
Springer Nature
Springer Nature B.V
Subjects
Alkenes
Aromatic compounds
Bromides
Chemistry
Chemistry and Materials Science
Chemistry, Organic
Halides
Ligands
Organic Chemistry
Palladium
Physical Sciences
Science & Technology
catalysis
palladium
trisubstituted alkenes
arylation
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Summary:One-pot sequential double arylation of terminal alkenes with aryl halides to give trisubstituted derivatives is reported. The proposed approach is more advantageous than the known methods due to the use of a combination of low reactive but available aryl bromides or aryl chlorides and palladium-based “ligand-free” catalytic system.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428023100044