Mesoporosity development in ZSM-5 zeolite upon optimized desilication conditions in alkaline medium

The development of porosity in ZSM-5 zeolite by desilication in alkaline medium has been studied. Treatment of ZSM-5 in NaOH solutions leads to mesoporosity development, stemming from the preferential extraction of Si from the zeolite framework. Investigation of the influence of temperature and time...

Full description

Saved in:
Bibliographic Details
Published inColloids and surfaces. A, Physicochemical and engineering aspects Vol. 241; no. 1; pp. 53 - 58
Main Authors Groen, J.C, Peffer, L.A.A, Moulijn, J.A, Pérez-Ramı́rez, J
Format Journal Article
LanguageEnglish
Published Elsevier B.V 14.07.2004
Subjects
Adsorption
Alkaline treatment
Bimodal porosity
Desilication
Mesopore formation
ZSM-5
Mesopore formation
Bimodal porosity
Alkaline treatment
Desilication
Adsorption
ZSM-5
Online AccessGet full text

Cover

More Information
Summary:The development of porosity in ZSM-5 zeolite by desilication in alkaline medium has been studied. Treatment of ZSM-5 in NaOH solutions leads to mesoporosity development, stemming from the preferential extraction of Si from the zeolite framework. Investigation of the influence of temperature and time during this treatment on the porous properties of the final material shows that the mesopore size and volume can be tuned to a certain extent by optimization of these two variables. Optimal treatment conditions lead to a spectacularly increased mesopore surface area (450%) from 40 m 2/g for the calcined zeolite to 225 m 2/g for the alkaline-treated material, while the micropore volume is only slightly decreased. The mesoporosity created under optimal conditions affects neither the long-range ordering nor the micropore-size.
ISSN:0927-7757
1873-4359
DOI:10.1016/j.colsurfa.2004.04.012