Delay-controlled reactions
When the entities undergoing a chemical reaction are not available simultaneously, the classical rate equation in the reaction-limited regime, should be extended by including non-Markovian memory effects. We consider the two cases of an external feedback, realized by fixed functions and an internal...
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Published in | Physics letters. A Vol. 321; no. 4; pp. 205 - 215 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
09.02.2004
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Subjects | |
Online Access | Get full text |
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Summary: | When the entities undergoing a chemical reaction are not available simultaneously, the classical rate equation in the reaction-limited regime, should be extended by including non-Markovian memory effects. We consider the two cases of an external feedback, realized by fixed functions and an internal feedback originated in a self-organized manner by the relevant concentration itself. Whereas in the first case the fixed points are not changed, although the dynamical process is altered, the second case offers a complete new behavior, characterized by the existence of a time persistent solution. As an example we consider a single-species pair annihilation
A+
A→∅ process combined with a spontaneous creation of particles ∅→
A. |
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ISSN: | 0375-9601 1873-2429 |
DOI: | 10.1016/j.physleta.2003.12.045 |