Delay-controlled reactions

When the entities undergoing a chemical reaction are not available simultaneously, the classical rate equation in the reaction-limited regime, should be extended by including non-Markovian memory effects. We consider the two cases of an external feedback, realized by fixed functions and an internal...

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Bibliographic Details
Published inPhysics letters. A Vol. 321; no. 4; pp. 205 - 215
Main Authors Trimper, Steffen, Zabrocki, Knud
Format Journal Article
LanguageEnglish
Published Elsevier B.V 09.02.2004
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Summary:When the entities undergoing a chemical reaction are not available simultaneously, the classical rate equation in the reaction-limited regime, should be extended by including non-Markovian memory effects. We consider the two cases of an external feedback, realized by fixed functions and an internal feedback originated in a self-organized manner by the relevant concentration itself. Whereas in the first case the fixed points are not changed, although the dynamical process is altered, the second case offers a complete new behavior, characterized by the existence of a time persistent solution. As an example we consider a single-species pair annihilation A+ A→∅ process combined with a spontaneous creation of particles ∅→ A.
ISSN:0375-9601
1873-2429
DOI:10.1016/j.physleta.2003.12.045