Synthesis of perfluorinated functionalized, branched ethers

Graphic We wish to report synthesis of perfluorinated functionalized, branched ethers from their hydrocarbon analogues by direct fluorination. Yields up to 90%, with high purities, have been obtained at ambient temperature and pressure. This technique will likely develop into a new general method fo...

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Bibliographic Details
Published inJournal of fluorine chemistry Vol. 125; no. 5; pp. 749 - 754
Main Authors Felling, Kyle W, Youngstrom, Cameron R, Lagow, Richard J
Format Journal Article
LanguageEnglish
Published LAUSANNE Elsevier B.V 01.05.2004
Elsevier
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Dendrimers
Direct fluorination
Hyperbranched polymers
Perfluorinated ethers
Physical Sciences
Science & Technology
Dendrimers
Perfluorinated ethers
Hyperbranched polymers
Direct fluorination
direct fluorination
dendrimers
MONODISPERSE
perfluorinated ethers
FLUORINATION
hyperbranched polymers
WATER
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Summary:Graphic We wish to report synthesis of perfluorinated functionalized, branched ethers from their hydrocarbon analogues by direct fluorination. Yields up to 90%, with high purities, have been obtained at ambient temperature and pressure. This technique will likely develop into a new general method for producing perfluorinated, hyperbranched and dendritic polymers.
ISSN:0022-1139
1873-3328
DOI:10.1016/j.jfluchem.2003.12.012