Relaxation, de Vries behavior, and layer contraction in chiral liquid crystal by dielectric spectroscopy
Low-frequency (LF) (20 Hz to 10 MHz) field response investigations are reported in TSiKN65F series-based chiral liquid crystal compound, C-10, viz., 1-[3ʹ-nitro-4ʹ-S-(2-decyloxy)phenyl]phenyl-4-(1,1,1,3,5,5,5-heptamethyltrisiloxydecyloxy)-3-Fluorobenzoate. Molecular frame with 10-methylene units and...
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Published in | Soft materials Vol. 16; no. 3; pp. 166 - 185 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
Taylor & Francis
03.07.2018
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Subjects | |
Online Access | Get full text |
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Summary: | Low-frequency (LF) (20 Hz to 10 MHz) field response investigations are reported in TSiKN65F series-based chiral liquid crystal compound, C-10, viz., 1-[3ʹ-nitro-4ʹ-S-(2-decyloxy)phenyl]phenyl-4-(1,1,1,3,5,5,5-heptamethyltrisiloxydecyloxy)-3-Fluorobenzoate. Molecular frame with 10-methylene units and a chiral center on one end is connected to the core with 3-phenyl rings. Other end of core connected to biforked trisiloxy chain to promote de Vries phase. Isotropic-smectic-A and smectic-A-smectic-C*
deVr
transitions are determined by capacitance study. DC field reversal and polarized optical microscopy textures confirmed occurrence of SmC*
deVr
phase below SmA. Hysteresis is observed in SmC*
deVr
. Tilt order parameter growth estimated in SmC*
deVr
phase through β equal to 0.673 agrees with mean field prediction. Relaxation behavior in kilo Hertz region is explained through longitudinal dipole moment μ
l
reorientation. Dynamics studied through LF dielectric relaxation infers dominance of order director fluctuations at few kilohertz. Higher activation energy in de Vries phase infers greater degrees of freedom and additional constraints. Loss ε″(T) exhibited anomalous trend at SmA-to-SmC*
deVr
interface. Temperature variation of tilt θ(T) is estimated from loss. Loss in de Vries phase gets suppressed by field to infer collective response. Curie-Weiss behavior by γ-exponent ~0.03 infers weaker ferroelectric response in SmC*
deVr
phase. Loss variation ε″(T) addressed by perturbed bookshelf model reveals marginal layer contraction by <1% in SmC*
deVr
phase. Estimates of layer shrinkage through R- and f-parameters in SmC*
deVr
phase confirm the de Vries behavior. |
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ISSN: | 1539-445X 1539-4468 |
DOI: | 10.1080/1539445X.2018.1461652 |