Kinetics of triplet excitation transport in disordered organic solids

The time dependence of triplet excitation energy transport in energetically disordered organic solids is studied. Contrary to the ensemble averaged hopping frequency ν( t)∼ t α( t)−1 with time dependent dispersion parameter α( t), we introduce the hopping rate in the form ν( t)∼( a+ bt) −1, without...

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Bibliographic Details
Published inChemical physics Vol. 297; no. 1; pp. 139 - 142
Main Authors Włodarczyk, Jakub, Kierdaszuk, Borys
Format Journal Article
LanguageEnglish
Published Elsevier B.V 16.02.2004
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Summary:The time dependence of triplet excitation energy transport in energetically disordered organic solids is studied. Contrary to the ensemble averaged hopping frequency ν( t)∼ t α( t)−1 with time dependent dispersion parameter α( t), we introduce the hopping rate in the form ν( t)∼( a+ bt) −1, without time dependent parameters. We show that such hopping rate leads to the power-like tail of luminescence decay function. The mechanism leading to time hierarchy in hopping phenomena is discussed.
ISSN:0301-0104
DOI:10.1016/j.chemphys.2003.10.021