Kinetically controlled narcissistic self-sorting of Pd()-linked self-assemblies from structurally similar tritopic ligands

Herein, we present the narcissistic self-sorted state from two kinds of structurally similar tritopic ligands with a cis -protected Pd( ii ) complex, which was generated by both the pathway-dependent process and the proper choice of the leaving ligand. This metastable state could not be attained by...

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Published inChemical communications (Cambridge, England) Vol. 58; no. 77; pp. 1829 - 1832
Main Authors Abe, Tsukasa, Horiuchi, Shinnosuke, Hiraoka, Shuichi
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 27.09.2022
Subjects
Ligands
Metastable state
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Summary:Herein, we present the narcissistic self-sorted state from two kinds of structurally similar tritopic ligands with a cis -protected Pd( ii ) complex, which was generated by both the pathway-dependent process and the proper choice of the leaving ligand. This metastable state could not be attained by simple mixing of all components by heating under thermodynamic control. A metastable narcissistic self-sorted state was generated from structurally similar tritopic ligands depending on the pathway and the leaving-ligand, which cannot be realized under thermodynamic control.
Bibliography:Electronic supplementary information (ESI) available. CCDC
For ESI and crystallographic data in CIF or other electronic format see DOI
https://doi.org/10.1039/d2cc04496j
2191967
2191966
and
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc04496j