The development of novel functionalised aryl cyanate esters. Part 2. Mechanical properties of the polymers and composites

• Published in: Polymer (Guilford) Vol. 42; no. 6; pp. 2307 - 2319
• Main Authors: HAMERTON, I, BARTON, J. M, CHAPLIN, A, HOWLIN, B. J, SHAW, S. J
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier 01.03.2001
• Subjects: Applied sciences; Exact sciences and technology; Forms of application and semi-finished materials; Laminates; Polymer industry, paints, wood; Technology of polymers; Bismaleimide resin; Polymer blends; Property composition relationship; Laminate; Allyl resin; Morphology; Mechanical properties; Fracture surface; Triazine derivative polymer; Experimental study; Carbon fiber
• ISSN: 0032-3861; 1873-2291
• DOI: 10.1016/S0032-3861(00)00410-9

Carbon fibre preimpregnated tape (prepreg) was prepared from a range of prepolymers comprising several different blends of alkenyl-functionalised cyanate ester (CE) monomers with commercial CE and bismaleimide (BMI) monomers and blends. Carbon fibre composites were prepared by autoclave moulding. Dynamic mechanical thermal analysis (DMTA) was used to assess cure cycles by the measurement of glass transition temperatures (T sub g ). Mechanical properties are reported for neat resins and compared with the corresponding composite properties such as interlaminar shear strength, flexural strength, compressive strength and mode I fracture toughness (G sub IC ). By incorporation of alkenyl-functionalised CE monomers into CE/BMI blends it is possible to raise the value of T sub g while maintaining levels of G sub IC (when compared with an unmodified BMI/CE blend) and without leading to a degradation in other mechanical properties. This enhancement in neat resin fracture toughness was translated into the corresponding composite. For example, a novel modifier 5rPOCN, at an incorporation level of 15% by weight, produces a composite with T sub g =170 deg C, interlaminar shear strength 113 MPa and G sub IC =513 J/m exp 2 , comparable with reported thermoplastic-toughened CE composites. Copyright (c) 2000 Elsevier Science Ltd