Functionalised organosulfur donor molecules: synthesis of racemic hydroxymethyl-, alkoxymethyl- and dialkoxymethyl-bis(ethylenedithio)tetrathiafulvalenes

Short synthetic routes to racemic derivatives of bis(ethylenedithio)tetrathiafulvalene carrying one hydroxymethyl (HMET), alkoxymethyl or dialkoxymethyl side chain are reported along with cyclic voltammetry measurements and conversion of HMET to (2:1) radical cation salts. Graphic

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Bibliographic Details
Published inTetrahedron Vol. 57; no. 23; pp. 5015 - 5026
Main Authors Saygili, Nezire, Brown, R.James, Day, Peter, Hoelzl, Robert, Kathirgamanathan, Poopathy, Mageean, Eileen R, Ozturk, Turan, Pilkington, Melanie, Qayyum, Mohammed M.B, Turner, Scott S, Vorwerg, Lars, Wallis, John D
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 04.06.2001
Elsevier
Subjects
bis(ethylenedithio)tetrathiafulvalenes
Chemistry
Chemistry, Organic
organic conductors
Physical Sciences
radical cation salts
Science & Technology
synthesis
synthesis
organic conductors
radical cation salts
bis(ethylenedithio)tetrathiafulvalenes
CYCLIC SULFATE ESTER
ACID
SALTS
CONDUCTORS
BIS(ETHYLENEDITHIO)TETRATHIAFULVALENE BEDT-TTF
METALS
RAY CRYSTAL-STRUCTURES
PRESSURE ORGANIC SUPERCONDUCTOR
DERIVATIVES
UNITS
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Summary:Short synthetic routes to racemic derivatives of bis(ethylenedithio)tetrathiafulvalene carrying one hydroxymethyl (HMET), alkoxymethyl or dialkoxymethyl side chain are reported along with cyclic voltammetry measurements and conversion of HMET to (2:1) radical cation salts. Graphic
ISSN:0040-4020
1464-5416
DOI:10.1016/S0040-4020(01)00432-X