Transition metal (Mo, Fe, Co, and Ni)-based catalysts for electrochemical CO2 reduction

• Published in: Chinese journal of catalysis Vol. 39; no. 7; pp. 1157 - 1166
• Main Authors: Hao, Jinhui, Shi, Weidong
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.07.2018
• Subjects: CO2; Electrocatalytic; Energy conversion; Transition metal; Electrocatalytic; Transition metal; Energy conversion; CO2
• ISSN: 1872-2067; 1872-2067
• DOI: 10.1016/S1872-2067(18)63073-6

The electrochemical conversion of CO2 into value-added chemicals and fuels has attracted widespread concern since it realizes the recycling of greenhouse gases. Production of new materials lies at the very core of this technology as it enables the improvement of developmental efficiency and selectivity by chemical optimization of morphology and electronic structure. Transition metal-based catalysts are particularly appealing as their d bands have valence electrons which are close to the Fermi level and hence overcome the intrinsic activation barriers and reaction kinetics. The study of Mo, Fe, Co, and Ni-based materials in particular is a very recent research subject that offers various possibilities in electrochemical CO2 reduction applications. Herein, we summarize the recent research progress of Mo, Fe, Co, and Ni-based catalysts and their catalytic behavior in electrochemical CO2 reduction. We particularly focus on the relationship between structures and properties, with examples of the key features accounting for the high efficiency and selectivity of the CO2 reduction process. The most significant experimental and theoretical improvements are highlighted. Finally, we concisely discuss the scientific challenges and opportunities for transition metal-based catalysts. Transition metal (Mo, Fe, Co and Ni)-based catalysts with well-defined d-state structure provided a fast electron transfer process for intermediate adsorption and thus exhibited high intrinsic activity for the electrochemical CO2 reduction process.