Perfluoroalkyl arsenicals X. Some reactions of secondary arsines and diarsines with fluoroolefins
The secondary arsines (CH 3) RAsH (R = CH 3, C 6H 5) react with the fluoroolefins X C=X(CF 2) nC F 4 (X = Cl, F; n = 1, 2) to yield (CH 3)RAs C=CX(CF 2) nC F 2 with elimination of HX. (CH 3) 2As-As(CH 3) 2 and Cl C(CF 2) nC F 2 afford (CH 3) 2− As C=CCl(CF 2) nC F 2 with elimination of ClAs(CH 3) 2....
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| Published in | Journal of organometallic chemistry Vol. 6; no. 4; pp. 364 - 372 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.01.1966
|
| Online Access | Get full text |
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| Summary: | The secondary arsines (CH
3) RAsH (R = CH
3, C
6H
5) react with the fluoroolefins X
C=X(CF
2)
nC
F
4 (X = Cl, F;
n = 1, 2) to yield (CH
3)RAs
C=CX(CF
2)
nC
F
2 with elimination of HX. (CH
3)
2As-As(CH
3)
2 and Cl
C(CF
2)
nC
F
2 afford (CH
3)
2− As
C=CCl(CF
2)
nC
F
2 with elimination of ClAs(CH
3)
2. (CH
3)
2AsMgBr reacts with CF
2=CFCF
3 and
CF=CFCF
2C
F
2 to give (CH
3)
2AsCF=CFCF
3 and (CH
3)
2As
C=CFCF
2C
F
2 respectively. (CH
3)
2AsCF
2CFHCF
3 is obtained from (CH
3)
2AsH and CF
3CF=CF
2. |
|---|---|
| ISSN: | 0022-328X 1872-8561 |
| DOI: | 10.1016/S0022-328X(00)81516-8 |