Fabrication of 3D hierarchical porous amidoxime-polyacrylonitrile spheres via nanoscale thermally induced phase separation with superhigh antimonate adsorption capacity

• Published in: Journal of cleaner production Vol. 310; p. 127400
• Main Authors: Tu, Yonghui, Ren, Long-Fei, Lin, Yuanxin, Zhou, H. Susan, Shao, Jiahui, He, Yiliang
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 10.08.2021
• Subjects: Amidoxime-polyacrylonitrile sphere; Antimonate adsorption; Hierarchical pores; Thermally induced phase separation; Amidoxime-polyacrylonitrile sphere; Thermally induced phase separation; Hierarchical pores; Antimonate adsorption
• ISSN: 0959-6526; 1879-1786
• DOI: 10.1016/j.jclepro.2021.127400

The traditional adsorbents for antimonate (Sb(V)) in industrial effluent suffered from poor adsorption capacity due to the lack of pores or adsorption sites. Three-dimensional (3D) amidoxime-polyacrylonitrile sphere (APANS) with hierarchical pores and abundant amidoxime groups was fabricated via nanoscale thermally induced phase separation (TIPS). The effects of fabrication parameters including diluent type, PAN concentration and amidoximation time on pore structure were studied with scanning electron microscopy (SEM), mercury intrusion instrument (MIP), fourier transform infrared spectrophotometer (FT-IR) and X-ray photoelectron spectroscopy (XPS). Results showed that APANS fabricated from 2% PAN/DMSO solution and amidoximated for 20 min had coarse surface, numerous mesopores, high porosity (88.5%) and large pore volume (20.5 mL/g). The pore formation mechanism revealed that the hierarchical pores were derived from multiscale DMSO crystals shaped by TIPS. Adsorption kinetics results showed that kinetics data were well fitted by pseudo-second-order model (R2 > 0.99) and the mesopores accelerated the adsorption (equilibrium time of 4 h) due to enormous surface excess and group exposure. Adsorption isotherm could be modeled by Freundlich (R2 > 0.99) and maximum adsorption capacity was 683.6 mg/g. The adsorption thermodynamics was also investigated, indicating the spontaneous and exothermic adsorption process. APANS exhibited excellent selectivity towards common anions (Cl−, SO42−, NO3− and PO43−) and reliable reusability (preserving 80% capacity after five cycles). This adsorbent provided a clean and sustainable strategy for Sb(V) removal from aqueous environment by superhigh capacity, fast rate and reliable reusability. [Display omitted] •Amidoxime-polyacrylonitrile sphere was synthesized via nanoscale TIPS.•The sphere possesses hierarchical pores and abundant amidoxime groups.•The sphere is an efficient adsorbent for antimonate removal from water.•The maximum adsorption capacity was found to be 683.6 mg/g.•Pore formation mechanism was identified using cold scanning electron microscopy.