Structural, vibrational, and enhanced magneto-electric coupling in Ho-substituted BiFeO3

• Published in: Journal of alloys and compounds Vol. 750; pp. 276 - 285
• Main Authors: Muneeswaran, Muniyandi, Lee, Seung Hoon, Kim, Dong Hun, Jung, Beon Sung, Chang, Seo Hyoung, Jang, Jae-Won, Choi, Byung Chun, Jeong, Jung Hyun, Giridharan, N.V., Venkateswaran, C.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 25.06.2018
• Subjects: Magneto-electric coupling; Raman spectroscopy; Structural phase transition; X-ray diffraction; Magneto-electric coupling; X-ray diffraction; Raman spectroscopy; Structural phase transition
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2018.03.365

The effect of Holmium (Ho) substitution in BiFeO3 [Bi1-xHoxFeO3 (x = 0.00, 0.05, 0.10, 0.15, 0.18, and 0.20)] ceramics is reported. The X-ray diffraction study shows composition-driven rhombohedral-to-orthorhombic (R3c to Pnma) phase transition for Bi1-xHoxFeO3 (x = 0.15, 0.18, and 0.20) which is confirmed by Reitveld refinement. Raman spectra of Bi1-xHoxFeO3 (x = 0.00, 0.05, and 0.10) belong to the rhombohedral (R3c) structure. Further increasing the Ho3+ concentration in a BiFeO3 (BFO) system revealed that Raman modes of Bi1-xHoxFeO3 (x = 0.15, 0.18 and 0.20) were assigned to an orthorhombic (pnma) structure, which is confirmed by the Rietveld analysis of X-ray diffraction data and TEM analysis. Ferroelectric studies show that the remnant polarization (Pr) gradually decreases for Bi1-xHoxFeO3 (x = 0.15, 0.18, and 0.20), confirming the transformation from polar to non-polar systems. Magnetic measurement shows ferromagnetic behavior observed for Bi1-xHoxFeO3 (x = 0.10 and 0.20) samples. Further, the magneto-electric coupling is measured in terms of magneto-capacitance of Ho3+-substituted BiFeO3 samples. •Ho3+ substituted BFO ceramics were synthesized by a solid-state reaction.•Structural transformation from rhombohedral (R3c) to orthorhombic (Pbnm).•Higher Ho3+ substituted BFO is assigned orthorhombic (Pbnm) by Raman studies.•Enhanced magneto-electric coupling observed in Ho3+ substituted BFO samples.