Magnetic nanocomposites of Fe3C or Ni-substituted (Fe3C/Fe3O4) with carbon for degradation of methylene orange and p-nitrophenol

• Published in: Journal of cleaner production Vol. 309; p. 127372
• Main Authors: Gangwar, Asnit, Singh, Ankit, Pal, Shaili, Sinha, Indrajit, Meena, Sher Singh, Prasad, Nand Kishore
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.08.2021
• Subjects: Heterogeneous catalysts; Iron carbide; Iron oxide; Nanocomposites; Photo-fenton degradation; Sol-gel method; Iron oxide; Nanocomposites; Heterogeneous catalysts; Iron carbide; Sol-gel method; Photo-fenton degradation
• ISSN: 0959-6526; 1879-1786
• DOI: 10.1016/j.jclepro.2021.127372

We report the structural and catalytic behavior for nanocomposites such as Fe3C/C, Fe3C/Fe3O4/C and Ni-substituted Fe3C/Fe3O4/C, which were synthesized by sol-gel route followed by calcination at 700 °C in N2 atmosphere. The structural and coexistence of the phases present in the nanocomposite were analyzed by X-ray and electron diffractions. The Mössbauer spectroscopy also supported above findings. The X-ray photoelectron spectroscopy designated oxidation states and bonding between the elements present in the composites. Magnetic properties measurements system was carried out to examine the effect of Ni substitution on the magnetic behaviors of the nanocomposites. The optical band gaps of the prepared nanomaterials were suitable for photocatalytic activity. Thus, the catalytic activities of these nanocomposites were evaluated during the degradation of methyl orange and p-nitrophenol under Fenton-like and photo-Fenton conditions. The optimum apparent catalytic reaction rate constant for Fe3C/Fe3O4/C with p-nitrophenol and methyl orange were ~1.48 x 10−2 and 3.36 x 10−2 mol−1 L−1 min−1, respectively. The catalysts were stable even after 5th cycles of catalytic experiments, and it was confirmed from their XRD patterns. [Display omitted] •Nanocomposites of Fe3C or Ni-doped (Fe3C/Fe3O4) with C, synthesized by sol-gel route.•XRD, TEM, Mössbauer spectra confirmed the coexistence of oxide and carbide phases.•The samples displayed suitable magnetic behavior for recycling.•Kapp for Fe3C/Fe3O4/C with PNP and MO were ~1.48 x10−2 and 3.36 x 10−2 mol Lit−1min−1.•Ni-substitution in nanocomposites enhances photo Fenton degradation of both pollutants.