Preparation of (Z)-1-halo-1-alkenes and (Z)-1-halo-2-alkoxy-1-alkenes using Cr(II/III) and Fe(0)
Reduction of 1, 1, 1-trihaloalkanes by Cr(II) or Cr(III) regenerated by Fe(0) in rnoist tetrahydrofuran at room temperature stereoselectively generates (Z)-1-halo-1-alkenes and (Z)-1-halo-2alkoxy-1-alkenes in good to excellent yields.
Saved in:
Published in | Synlett no. 16; pp. 2652 - 2654 |
---|---|
Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
STUTTGART
Thieme Medical Publishers
04.10.2006
|
Subjects | |
Online Access | Get more information |
Cover
Loading…
Summary: | Reduction of 1, 1, 1-trihaloalkanes by Cr(II) or Cr(III) regenerated by Fe(0) in rnoist tetrahydrofuran at room temperature stereoselectively generates (Z)-1-halo-1-alkenes and (Z)-1-halo-2alkoxy-1-alkenes in good to excellent yields. |
---|---|
ISSN: | 0936-5214 |
DOI: | 10.1055/s-2006-951467 |