The Effect of Lengthening Cation Ether Tails on Ionic Liquid Properties

• Published in: ECS transactions Vol. 75; no. 15; pp. 215 - 232
• Main Authors: Lall-Ramnarine, Sharon, Rodriguez, Chanele, Fernandez, Rahonel, Zmich, Nicole, Fernandez, Eddie, Dhiman, Surajdevparkash, Wishart, James F.
• Format: Journal Article
• Language: English
• Published: United States The Electrochemical Society, Inc 30.08.2016; Electrochemical Society
• Subjects: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
• ISSN: 1938-5862; 1938-6737; 1938-6737
• DOI: 10.1149/07515.0215ecst

In order to explore the effect of multiple ether functionalities on ionic liquid properties, a series of ten pyrrolidinium ionic liquids and ten imidazolium ionic liquids bearing ether and alkyl side chains of varying lengths (4 to 10 atoms in length) were prepared. Their physical properties, such as viscosity, conductivity and thermal profile were measured and compared. Consistent with earlier literature, a single ether substituent substantially decreases the viscosity of pyrrolidinium and imidazolium ILs compared to their alkyl congeners. Remarkably, as the number of ether units in the pyrrolidinium ILs increases there is hardly any increase in the viscosity, in contrast to alkylpyrrolidinium ILs where the viscosity increases steadily with chain length. Viscosities of imidazolium ether ILs increase with chain length but always remain well below their alkyl congeners. These results provide significant insight on the choice of starting materials for researchers designing ILs for specific applications.