Palladium catalyzed hydroamination of conjugated enynes

The [( η 3-C 3H 5)PdCl] 2-dppf-AcOH catalytic system effected the hydroamination of conjugated enynes 1 leading to the formation of (E)-isomer of alkenic 1,4-diamines in stereoselective fashion. The combination [( η 3-C 3H 5)PdCl] 2-dppf-AcOH system catalyzed the hydroamination of conjugated enynes....

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Bibliographic Details
Published inTetrahedron letters Vol. 39; no. 9; pp. 1037 - 1040
Main Authors Radhakrishnan, Ukkiramapandian, Al-Masum, Mohammad, Yamamoto, Yoshinori
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 26.02.1998
Elsevier
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
REACTIVITY
CARBONYLATION
ALKYNES
AMINES
DERIVATIVES
COMPLEXES
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Summary:The [( η 3-C 3H 5)PdCl] 2-dppf-AcOH catalytic system effected the hydroamination of conjugated enynes 1 leading to the formation of (E)-isomer of alkenic 1,4-diamines in stereoselective fashion. The combination [( η 3-C 3H 5)PdCl] 2-dppf-AcOH system catalyzed the hydroamination of conjugated enynes.
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(97)10697-9