The 3D CuO (tenorite) as copper-ion source afforded the first 1,4-naphthalenedicarboxylate bridged coordination dimmer linked via triple-hydrogen-bonding water molecule into a 2D network

The reaction of three-dimensional (3D) CuO (tenorite) with 1,4-naphthalenedicarboxylic acid and 2,2 ′-dipyridylamine under hydrothermal conditions produced the first 1,4-naphthalenedicarboxylate bridged coordination dimmer linked via hydrogen-bonding water molecule into a two-dimensional (2D) networ...

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Bibliographic Details
Published inInorganic chemistry communications Vol. 5; no. 12; pp. 1028 - 1030
Main Authors Lu, Jack Y., Schauss, Vaughn
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.12.2002
Subjects
Coordination polymer
Copper oxide
Hydrogen bonds
Hydrothermal reaction
Naphthalenedicarboxylate
Two-dimensional structure
Two-dimensional structure
Hydrogen bonds
Copper oxide
Naphthalenedicarboxylate
Coordination polymer
Hydrothermal reaction
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Summary:The reaction of three-dimensional (3D) CuO (tenorite) with 1,4-naphthalenedicarboxylic acid and 2,2 ′-dipyridylamine under hydrothermal conditions produced the first 1,4-naphthalenedicarboxylate bridged coordination dimmer linked via hydrogen-bonding water molecule into a two-dimensional (2D) network structure. Instead of using simple inorganic salts, the 3D solid-state CuO was used as the copper-ion source for the reaction. The hydrogen-bonding water molecules in the network structure were completely lost below 250 °C and the dimmer was decomposed from 250 to 310 °C.
ISSN:1387-7003
1879-0259
DOI:10.1016/S1387-7003(02)00637-8