Raman spectra of cyclopentadienyl complexes (ith 5-C 5H 5) 2M (M = Mn, Cr, V, Ru, Os)

The Raman spectra of several dicyclopentadienyl complexes Cp 2M of transition metals (M  Mn, Cr, V, Ru, Os) are obtained in the solid and liquid states and are discussed together with the infrared data. The assignment of some Cp-vibrations is revised and a new assignment is proposed. The observed d...

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Published inJournal of organometallic chemistry Vol. 124; no. 3; pp. 293 - 298
Main Authors Aleksanyan, V.T., Lokshin, B.V., Borisov, G.K., Devyatykh, G.G., Smirnov, A.S., Nazarova, R.V., Koningstein, J.A., Gächter, B.F.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.01.1977
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Summary:The Raman spectra of several dicyclopentadienyl complexes Cp 2M of transition metals (M  Mn, Cr, V, Ru, Os) are obtained in the solid and liquid states and are discussed together with the infrared data. The assignment of some Cp-vibrations is revised and a new assignment is proposed. The observed difference between the Raman spectra of the low temperature amber-brown form and the rose form of manganocene is considered as a manifestation of a possible equilibrium between two different isomers of the compound in its low-temperature form.
ISSN:0022-328X
1872-8561
DOI:10.1016/S0022-328X(00)92593-2