Wrapping up Metal–Organic Framework Crystals with Carbon Nanotubes

The presence of tetrazine units in the organic nodes of UiO‐68‐TZCD controls the formation of ultrathin coatings of single‐wall nanotubes that decorate the surface of the crystal. These crystal hybrids can be prepared straightforwardly in one step and are extraordinarily respectful with the properti...

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Bibliographic Details
Published inAdvanced functional materials Vol. 33; no. 41
Main Authors Lerma‐Berlanga, Belén, M. Padial, Natalia, Galbiati, Marta, Brotons‐Alcázar, Isaac, Albero, Josep, García, Hermenegildo, Forment‐Aliaga, Alicia, Ganivet, Carolina R., Martí‐Gastaldo, Carlos
Format Journal Article
LanguageEnglish
Published Hoboken Wiley Subscription Services, Inc 01.10.2023
Subjects
Carbon nanotubes
Crystals
Materials science
Metal-organic frameworks
Room temperature
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Summary:The presence of tetrazine units in the organic nodes of UiO‐68‐TZCD controls the formation of ultrathin coatings of single‐wall nanotubes that decorate the surface of the crystal. These crystal hybrids can be prepared straightforwardly in one step and are extraordinarily respectful with the properties of the framework for combination of mesoporosity and surface areas ≈4.000 m 2 g −1 , with excellent stability in water, and conductivities at room temperature of 4 × 10 −2 S cm −1 even at very low carbon weight contents (2.3 wt.%).
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ISSN:1616-301X
1616-3028
DOI:10.1002/adfm.202302246