Crystal structure of a carboxylate-bridged one-dimensional linear chain polymer N-salicylidene-2-amino-phenylacidato copper(II) complex

A novel chain complex has been synthesized and its crystal structure was determined by X-ray diffraction technique. The crystal structure determination of C 14H 9CuNO 4·CH 3OH reveals that the local coordination geometry around Cu(II) is a tetrahedrally distorted square planar coordination and the C...

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Bibliographic Details
Published inJournal of molecular structure Vol. 643; no. 1; pp. 129 - 133
Main Authors Wang, Jun, Bei, Feng Li, Yang, Xu Jie, Lu, Lu De, Wang, Xin
Format Journal Article
LanguageEnglish
Published Elsevier B.V 19.12.2002
Subjects
Copper(II)
Crystal structure
One-dimensional chain
Salicylaldehyde
Schiff base
Schiff base
One-dimensional chain
Salicylaldehyde
Copper(II)
Crystal structure
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Summary:A novel chain complex has been synthesized and its crystal structure was determined by X-ray diffraction technique. The crystal structure determination of C 14H 9CuNO 4·CH 3OH reveals that the local coordination geometry around Cu(II) is a tetrahedrally distorted square planar coordination and the C 14H 9CuNO 4·CH 3OH is bridged by carboxylate oxygen atom to form an infinite one-dimensional linear chain. The crystal is a monoclinic, space group P2(1) with a=9.6650(19) A ̊ , b=7.1280(14) A ̊ , c=9.925(2) A ̊ , α=90°, β=98.39(3)°, γ=90° and Z=2.
ISSN:0022-2860
1872-8014
DOI:10.1016/S0022-2860(02)00400-3