An investigation into the β-cleavage of aziridinylcarbinyl radicals

In contrast to similar oxiranylcarbinyl radical systems, 3-arylaziridinylcarbinyl radicals have been shown to give only products of CN bond cleavage. Only products of CN bond leavage have been isolated in radical reactions with 3-arylaziridines

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Bibliographic Details
Published inTetrahedron letters Vol. 40; no. 26; pp. 4873 - 4876
Main Authors Marples, Brian A., Toon, Richard C.
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 25.06.1999
Elsevier
Subjects
amines
Aziridines
Chemistry
Chemistry, Organic
cleavage reactions
Physical Sciences
radical
Science & Technology
amines
Aziridines
radical
cleavage reactions
REARRANGEMENT
aziridines
RING EXPANSION
OXIRANYLCARBINYL RADICALS
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Summary:In contrast to similar oxiranylcarbinyl radical systems, 3-arylaziridinylcarbinyl radicals have been shown to give only products of CN bond cleavage. Only products of CN bond leavage have been isolated in radical reactions with 3-arylaziridines
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(99)00900-4