Application of Aqai Stalks as Biosorbents for the Removal of the Dye Procion Blue MX-R from Aqueous Solution

• Published in: Separation science and technology Vol. 47; no. 3; pp. 513 - 526
• Main Authors: Alencar, Wagner S., Lima, Eder C., Royer, Betina, dos Santos, Bruna D., Calvete, Tatiana, da Silva, Edson A., Alves, Claudio N.
• Format: Journal Article
• Language: English
• Published: Taylor & Francis Group 01.02.2012
• Subjects: adsorption; biosorption; general order kinetic equation; kinetic parameters; thermodynamics; wastewater treatment
• ISSN: 0149-6395; 1520-5754
• DOI: 10.1080/01496395.2011.616568

The aqai palm stalk (Euterpe oleracea) is a food residue used in its natural form (AS) and also protonated (AAS) as biosorbents for the removal of the textile dye Procion Blue MX-R from aqueous solutions. This biosorbent was characterized by infrared spectroscopy, scanning electron microscopy, and nitrogen adsorption-desorption curves. The effects of pH, biosorbent dosages, and shaking time on the biosorption capacities were studied. In the acidic pH region (pH 2.0) the biosorption of the dye was favorable. The minimum contact time to obtain the equilibrium was 8 hours for AS and AAS biosorbents. The general order kinetic model provided the best fit to the experimental data compared with the pseudo-first order and pseudo-second order kinetic adsorption models. The equilibrium data were fitted to the Langmuir, Freundlich, and Sips isotherm models. For both dyes the equilibrium data were best fitted to the Sips isotherm model. The enthalpy and entropy of adsorption of PB were obtained from adsorption equilibrium experiments ranging from 298 to 323 K. Simulated dyehouse effluent was used to check the applicability of the proposed adsorbents for effluent treatment.