Studies directed toward the synthesis of viridenomycin. Route 2: a second generation approach

A second generation approach toward the synthesis of viridenomycin is described. Three key fragments of the molecule have been synthesized in stereochemically pure form. Initial studies toward the coupling of these fragments with the aim of assembling the macrocycle are detailed. Final efforts to re...

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Bibliographic Details
Published inTetrahedron letters Vol. 42; no. 26; pp. 4305 - 4308
Main Authors Waterson, Alex G, Kruger, Albert W, Meyers, A.I
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 25.06.2001
Elsevier
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
OLEFINATION
REAGENTS
CYCLIC SULFATES
STEREOCHEMISTRY
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Summary:A second generation approach toward the synthesis of viridenomycin is described. Three key fragments of the molecule have been synthesized in stereochemically pure form. Initial studies toward the coupling of these fragments with the aim of assembling the macrocycle are detailed. Final efforts to reach the title compound are documented. Graphic
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(01)00701-8