Carbonium ion derived from substituted π-allylpalladium chloride complexes
Cationic butadienylpalladium chloride complexes, assumed to be intermediates in the nucleophilic substitutions at [1-(1-chloroalkyl)π-allyl]palladium chlorides, can be prepared by abstraction of chloride from [1-(1-chloroalkyl)-π-allyl]- or hydride from (1-alkyl-π-allyl)palladium chlorides by strong...
Saved in:
| Published in | Journal of organometallic chemistry Vol. 31; no. 1; pp. 111 - 118 |
|---|---|
| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.01.1971
|
| Online Access | Get full text |
Cover
Loading…
| Summary: | Cationic butadienylpalladium chloride complexes, assumed to be intermediates in the nucleophilic substitutions at [1-(1-chloroalkyl)π-allyl]palladium chlorides, can be prepared by abstraction of chloride from [1-(1-chloroalkyl)-π-allyl]- or hydride from (1-alkyl-π-allyl)palladium chlorides by strong acids or SbF
5. NMR data indicate that the butadienyl group is bonded as a cisoid,
tetrahapto ligand.
Solutions of a cationic (trimethylenemethane palladium complex can be obtained analogously by chloride abstraction from [2-(dichloromethyl)-π-allyl]palladium chloride. |
|---|---|
| ISSN: | 0022-328X 1872-8561 |
| DOI: | 10.1016/S0022-328X(00)87470-7 |