Synthetic study of tautomycetin: Synthesis of two large subunits

Two large subunits for synthesis of tautomycetin have been synthesized. Two large subunits for synthesis of tautomycetin have been synthesized. Efficient construction of the dienone moiety has been achieved by regioselective hydrostannylation of an internal alkyne and subsequent Stille coupling.

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Bibliographic Details
Published inTetrahedron letters Vol. 38; no. 45; pp. 7897 - 7900
Main Authors Oikawa, Hideaki, Yoneta, Yasushi, Ueno, Tohru, Oikawa, Masato, Wakayama, Tomomi, Ichihara, Akitami
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 10.11.1997
Elsevier
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
protein phosphatase inhibitor
Science & Technology
tautomycetin
tautomycin
tautomycetin
protein phosphatase inhibitor
tautomycin
ALCOHOLS
PALLADIUM
ALDEHYDES
ALKYNES
ANHYDRIDE
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Summary:Two large subunits for synthesis of tautomycetin have been synthesized. Two large subunits for synthesis of tautomycetin have been synthesized. Efficient construction of the dienone moiety has been achieved by regioselective hydrostannylation of an internal alkyne and subsequent Stille coupling.
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(97)10100-9