A novel synthesis of functionalised tertiary phosphines by palladium catalysed phosphination with triarylphosphines

The palladium catalysed Pd-aryl/P-aryl exchange was applied in the synthesis of various functionalised phosphines from their corresponding substituted aryl triflates using triarylphosphines as the phosphinating agents. This method tolerated many functional groups including ketone, aldehyde, ester, n...

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Bibliographic Details
Published inTetrahedron letters Vol. 41; no. 52; pp. 10285 - 10289
Main Authors Kwong, Fuk Yee, Lai, Chi Wai, Tian, Yuan, Chan, Kin Shing
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 23.12.2000
Elsevier
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
HALIDES
BINAP
VINYLPHOSPHONIUM SALTS
VINYLATION
PHOSPHINYLATION
COMPLEXES
CONVENIENT
ASYMMETRIC HYDROGENATION
TRIPHENYLPHOSPHINE
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Summary:The palladium catalysed Pd-aryl/P-aryl exchange was applied in the synthesis of various functionalised phosphines from their corresponding substituted aryl triflates using triarylphosphines as the phosphinating agents. This method tolerated many functional groups including ketone, aldehyde, ester, nitrile, methyl ether, pyridyl and chloride groups.
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(00)01850-5