Photoinduced formation of persistent contact ion pairs in solid noble gases: UV/Vis spectroscopic, photokinetic and energetic investigations

A preceding study on persistent contact ion pairs (CIPs) which had been produced by Hg lamp irradiation of solid argon doped with N, N, N ′, N ′-tetramethyl- p-phenylenediamine and tetrachloromethane is extended to N, N, N ′, N ′-tetramethylbenzidine as a further donor and xenon as an additional sol...

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Published inChemical physics Vol. 261; no. 3; pp. 339 - 352
Main Authors Gödicke, Björn, Langenscheidt, Andreas, Meyer, Hermann, Schweig, Armin
Format Journal Article
LanguageEnglish
Published Elsevier B.V 15.11.2000
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Abstract A preceding study on persistent contact ion pairs (CIPs) which had been produced by Hg lamp irradiation of solid argon doped with N, N, N ′, N ′-tetramethyl- p-phenylenediamine and tetrachloromethane is extended to N, N, N ′, N ′-tetramethylbenzidine as a further donor and xenon as an additional solid medium. Experimental and theoretical ultraviolet/visible absorption spectroscopic and photokinetic investigations as well as energetic considerations lead to a more detailed understanding of the formation and properties of the CIPs.
AbstractList A preceding study on persistent contact ion pairs (CIPs) which had been produced by Hg lamp irradiation of solid argon doped with N, N, N ′, N ′-tetramethyl- p-phenylenediamine and tetrachloromethane is extended to N, N, N ′, N ′-tetramethylbenzidine as a further donor and xenon as an additional solid medium. Experimental and theoretical ultraviolet/visible absorption spectroscopic and photokinetic investigations as well as energetic considerations lead to a more detailed understanding of the formation and properties of the CIPs.
Author Schweig, Armin
Langenscheidt, Andreas
Gödicke, Björn
Meyer, Hermann
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Snippet A preceding study on persistent contact ion pairs (CIPs) which had been produced by Hg lamp irradiation of solid argon doped with N, N, N ′, N ′-tetramethyl-...
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Title Photoinduced formation of persistent contact ion pairs in solid noble gases: UV/Vis spectroscopic, photokinetic and energetic investigations
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