Photoinduced formation of persistent contact ion pairs in solid noble gases: UV/Vis spectroscopic, photokinetic and energetic investigations

A preceding study on persistent contact ion pairs (CIPs) which had been produced by Hg lamp irradiation of solid argon doped with N, N, N ′, N ′-tetramethyl- p-phenylenediamine and tetrachloromethane is extended to N, N, N ′, N ′-tetramethylbenzidine as a further donor and xenon as an additional sol...

Full description

Saved in:
Bibliographic Details
Published inChemical physics Vol. 261; no. 3; pp. 339 - 352
Main Authors Gödicke, Björn, Langenscheidt, Andreas, Meyer, Hermann, Schweig, Armin
Format Journal Article
LanguageEnglish
Published Elsevier B.V 15.11.2000
Online AccessGet full text

Cover

More Information
Summary:A preceding study on persistent contact ion pairs (CIPs) which had been produced by Hg lamp irradiation of solid argon doped with N, N, N ′, N ′-tetramethyl- p-phenylenediamine and tetrachloromethane is extended to N, N, N ′, N ′-tetramethylbenzidine as a further donor and xenon as an additional solid medium. Experimental and theoretical ultraviolet/visible absorption spectroscopic and photokinetic investigations as well as energetic considerations lead to a more detailed understanding of the formation and properties of the CIPs.
ISSN:0301-0104
DOI:10.1016/S0301-0104(00)00293-7