Synthesis of novel chiral non-racemic substituted trianglimine and trianglamine macrocycles

The synthesis of novel 27- and 30-membered macrocycles of the trianglimine and trianglamine type is described, based on a [3+3] cyclocondensation between an enantiomerically pure 1,2-diamine and aromatic dicarboxaldehydes. Novel substituted trianglimines and trianglamines are synthesised using a [3+...

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Bibliographic Details
Published inTetrahedron letters Vol. 43; no. 18; pp. 3329 - 3332
Main Authors Kuhnert, Nikolai, Lopez-Periago, Ana M.
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 29.04.2002
Elsevier
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
TRANSITION-METAL COMPLEXES
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ISSN0040-4039
1873-3581
DOI10.1016/S0040-4039(02)00523-3

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Summary:The synthesis of novel 27- and 30-membered macrocycles of the trianglimine and trianglamine type is described, based on a [3+3] cyclocondensation between an enantiomerically pure 1,2-diamine and aromatic dicarboxaldehydes. Novel substituted trianglimines and trianglamines are synthesised using a [3+3] cyclocondensation.
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(02)00523-3