Detection of a π–π complex by diffusion-ordered spectroscopy (DOSY)

Diffusion-ordered NMR spectroscopy (DOSY) has been used in the detection of π–π complexes formed through π–π stacking interactions of a hydrophobic compound in concentrated aqueous solutions. π–π stacked complexes of metolachlor have been identified by DOSY.

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Bibliographic Details
Published inTetrahedron letters Vol. 43; no. 14; pp. 2515 - 2519
Main Authors Viel, Stéphane, Mannina, Luisa, Segre, Annalaura
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.04.2002
Subjects
diffusion-ordered spectroscopy
DOSY
NMR
stacking interaction
π–π complex
DOSY
NMR
diffusion-ordered spectroscopy
stacking interaction
π–π complex
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Summary:Diffusion-ordered NMR spectroscopy (DOSY) has been used in the detection of π–π complexes formed through π–π stacking interactions of a hydrophobic compound in concentrated aqueous solutions. π–π stacked complexes of metolachlor have been identified by DOSY.
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(02)00333-7