The effect of replacing carbonyl groups by other ligands on the catalytic properties of arenechromium carbonyl complexes

The activities of a series of areneCr(CO) 2L complexes in catalytic hydrogenation has been studied and found to be poorer than those of the Cr(CO) 3 analogs. The IR v(CO) changes of these complexes in THF have been shown to have value in predicting catalytic properties.

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Bibliographic Details
Published inJournal of organometallic chemistry Vol. 184; no. 1; pp. 91 - 101
Main Authors Dabard, R., Jaouen, G., Simonneaux, G., Cais, Michael, Kohn, D.H., Lapid, A., Tatarsky, D.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.01.1980
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Summary:The activities of a series of areneCr(CO) 2L complexes in catalytic hydrogenation has been studied and found to be poorer than those of the Cr(CO) 3 analogs. The IR v(CO) changes of these complexes in THF have been shown to have value in predicting catalytic properties.
ISSN:0022-328X
1872-8561
DOI:10.1016/S0022-328X(00)94366-3