Elucidation of the mechanism of an aromatic substitution reaction by the utilization of micelles as mechanistic probes

A mechanistic study has been performed in order to elucidate the mechanism of the iodination of aniline and the iodination species in this reaction. For this purpose, the reaction has been performed in the presence of cationic and anionic surfactants in order to utilize from micellar charge effect....

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Published inColloids and surfaces. A, Physicochemical and engineering aspects Vol. 173; no. 1; pp. 101 - 107
Main Authors Taşcıoğlu, Senay, Burcu Gürdere, M.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 10.11.2000
Subjects
Aniline
lodination
Mechanistic probes
Micelles
Reaction mechanism
Reaction mechanism
lodination
Aniline
Micelles
Mechanistic probes
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Summary:A mechanistic study has been performed in order to elucidate the mechanism of the iodination of aniline and the iodination species in this reaction. For this purpose, the reaction has been performed in the presence of cationic and anionic surfactants in order to utilize from micellar charge effect. The results of this study provided evidence to support the hyphothesis that the iodination reagent in this reaction is hypoiodous acid.
ISSN:0927-7757
1873-4359
DOI:10.1016/S0927-7757(00)00575-6