Preparation of Orthogonal π-Conjugated Aryl Alkynes and Cyclophanes

A series of anthracene based orthogonal π-conjugated aryl alkynes was prepared using palladium-catalyzed couplings. Thia- and azacyclophanes were prepared from anthracene based orthogonal π-conjugated aryl alkynes.

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Bibliographic Details
Published inTetrahedron Vol. 56; no. 42; pp. 8335 - 8344
Main Authors Crisp, Geoffrey T, Turner, Peter D
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 13.10.2000
Elsevier
Subjects
arylalkenes
Chemistry
Chemistry, Organic
cyclophanes
Physical Sciences
Science & Technology
π-conjugated
cyclophanes
π-conjugated
arylalkenes
pi-conjugated
ACIDS
DERIVATIVES
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Summary:A series of anthracene based orthogonal π-conjugated aryl alkynes was prepared using palladium-catalyzed couplings. Thia- and azacyclophanes were prepared from anthracene based orthogonal π-conjugated aryl alkynes.
ISSN:0040-4020
1464-5416
DOI:10.1016/S0040-4020(00)00741-9