Cationic Areneallyldicarbonylchromium complexes

The proton cleavage of chelate dicarbonylchromium complexes in the presence of benzyl and phenyl allyl ethers are shown to result in the formation of the formerly unknown cationic areneallyldicarbonylchromium complexes. We describe the general one step synthesis of these compounds upon ultra-violet...

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Published inJournal of organometallic chemistry Vol. 209; no. 3; pp. 309 - 321
Main Authors Nesmeyanov, A.N., Krivykh, V.V., Il'Minskaya, E.S., Rybinskaya, M.I.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.01.1981
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Summary:The proton cleavage of chelate dicarbonylchromium complexes in the presence of benzyl and phenyl allyl ethers are shown to result in the formation of the formerly unknown cationic areneallyldicarbonylchromium complexes. We describe the general one step synthesis of these compounds upon ultra-violet irradiation of arenetricarbonylchromium compounds and allyl alcohol and its derivatives in the presence of hydrofluoroboric acid. We obtained the formerly unknown cationic arenedicarbonyl complexes with a π-oxyallyl ligand when we used propargyl alcohol in this reaction.
ISSN:0022-328X
1872-8561
DOI:10.1016/S0022-328X(00)81189-4