Lithiosilanes and their application to the synthesis of polysilane dendrimers

An account is given of the preparation and structural investigations of silyllithium compounds, including X-ray and NMR data. This review covers the chemistry of lithiosilanes with alkyl, aryl, functional substituents and lithiooligosilanes with SiSi bonds. Application of lithiosilanes for the synt...

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Bibliographic Details
Published inCoordination chemistry reviews Vol. 210; no. 1; pp. 11 - 45
Main Authors Sekiguchi, Akira, Lee, Vladimir Ya, Nanjo, Masato
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.12.2000
Subjects
Dendrimer
Group I metals
Polysilane
Silicon derivatives
Silyllithium compounds
Polysilane
Dendrimer
Silyllithium compounds
Group I metals
Silicon derivatives
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Summary:An account is given of the preparation and structural investigations of silyllithium compounds, including X-ray and NMR data. This review covers the chemistry of lithiosilanes with alkyl, aryl, functional substituents and lithiooligosilanes with SiSi bonds. Application of lithiosilanes for the synthesis of polysilane dendritic molecules is also described.
ISSN:0010-8545
1873-3840
DOI:10.1016/S0010-8545(00)00315-5