4′-Functionalized 2,2′:6′,2″-terpyridines as building blocks for supramolecular chemistry and nanoscience

Different mono- and bis-terpyridines were synthesized utilizing nucleophilic substitution of 4′-chloro-2,2′:6′,2″-terpyridine. In the case of the mono-functionalized ligands, different functional groups opposite to the metal binding site could be introduced; with the bis-functionalized ligands build...

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Bibliographic Details
Published inTetrahedron letters Vol. 42; no. 28; pp. 4705 - 4707
Main Authors Schubert, Ulrich S, Eschbaumer, Christian, Hien, Oliver, Andres, Philip R
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 09.07.2001
Elsevier
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
COORDINATION POLYMERS
CONNECTIVITY
SEGMENTS
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Summary:Different mono- and bis-terpyridines were synthesized utilizing nucleophilic substitution of 4′-chloro-2,2′:6′,2″-terpyridine. In the case of the mono-functionalized ligands, different functional groups opposite to the metal binding site could be introduced; with the bis-functionalized ligands building blocks for metal-containing polymers with a tailored alkyl-chain length were accessible. As examples, a functionalized terpyridine cadmium(II) complex as well as a fullerene derivative were prepared. Graphic
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(01)00796-1