4′-Functionalized 2,2′:6′,2″-terpyridines as building blocks for supramolecular chemistry and nanoscience
Different mono- and bis-terpyridines were synthesized utilizing nucleophilic substitution of 4′-chloro-2,2′:6′,2″-terpyridine. In the case of the mono-functionalized ligands, different functional groups opposite to the metal binding site could be introduced; with the bis-functionalized ligands build...
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Published in | Tetrahedron letters Vol. 42; no. 28; pp. 4705 - 4707 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
OXFORD
Elsevier Ltd
09.07.2001
Elsevier |
Subjects | |
Online Access | Get full text |
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Summary: | Different mono- and bis-terpyridines were synthesized utilizing nucleophilic substitution of 4′-chloro-2,2′:6′,2″-terpyridine. In the case of the mono-functionalized ligands, different functional groups opposite to the metal binding site could be introduced; with the bis-functionalized ligands building blocks for metal-containing polymers with a tailored alkyl-chain length were accessible. As examples, a functionalized terpyridine cadmium(II) complex as well as a fullerene derivative were prepared.
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ISSN: | 0040-4039 1873-3581 |
DOI: | 10.1016/S0040-4039(01)00796-1 |