Synthesis and characterization of a MoO3–pyrrolidinedithiocarbamate hybrid

By using lamellar molybdenum trioxide, MoO3, and ammonium pyrrolidinedithiocarbamate (1-pyrrolidinecarbodithioic acid, ammonium salt), apdc, as precursors, an inorganic–organic intercalation hybrid of formula MoO3·0.54apdc was synthesized, which was characterized by CHN elemental analysis, infrared...

Full description

Saved in:
Bibliographic Details
Published inThe international journal of inorganic materials Vol. 3; no. 7; pp. 931 - 935
Main Author de Farias, R.F
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.11.2001
Subjects
Hybrids
Lamellar compounds
Molybdenum oxide
Molybdenum oxide
Hybrids
Lamellar compounds
Online AccessGet full text

Cover

More Information
Summary:By using lamellar molybdenum trioxide, MoO3, and ammonium pyrrolidinedithiocarbamate (1-pyrrolidinecarbodithioic acid, ammonium salt), apdc, as precursors, an inorganic–organic intercalation hybrid of formula MoO3·0.54apdc was synthesized, which was characterized by CHN elemental analysis, infrared spectroscopy, X-ray diffraction and SEM microscopy. After intercalation, the interlayer distance is increased from 0.7 (MoO3) to 1.2 nm (hybrid). The use of lamellar MoO3 as a molecular sieve for apdc and similar organic species is proposed.
ISSN:1466-6049
1466-6049
DOI:10.1016/S1466-6049(01)00082-4