Demonstration of reversible CC bond cleavage in oxiranylcarbinyl radicals

The incorporation of a stereochemical probe into aryl substituted oxiranylcarbinyl radicals has demonstrated that the CC bond cleavage in these systems is reversible, and that it can occur even when no products of CC cleavage are obtained. A stereochemical probe has been used to demonstrate the re...

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Bibliographic Details
Published inTetrahedron letters Vol. 38; no. 20; pp. 3599 - 3602
Main Authors Marples, Brian A., Rudderham, John A., Slawin, Alexandra M.Z., Edwards, Andrew J., Hird, Nicholas W.
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 19.05.1997
Elsevier
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
CHEMISTRY
CYCLOPENTANOLS
ALPHA-IODOEPOXIDES
INDUCED EPOXIDE FRAGMENTATION
CARBOCYCLES
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Summary:The incorporation of a stereochemical probe into aryl substituted oxiranylcarbinyl radicals has demonstrated that the CC bond cleavage in these systems is reversible, and that it can occur even when no products of CC cleavage are obtained. A stereochemical probe has been used to demonstrate the reversible CC cleavage of aryl-substituted oxiranylcarbinyl radicals.
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(97)00673-4