Infrared vibrational band shapes in excited states

This article describes the behaviour of the shapes of the IR bands of coordination compounds on electronic excitation. Broadening on excitation is frequently, but not invariably, observed; any broadening is the result of a subtle interplay of the properties of the vibrational mode, the excited state...

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Bibliographic Details
Published inCoordination chemistry reviews Vol. 230; no. 1; pp. 213 - 224
Main Author Turner, James J
Format Journal Article
LanguageEnglish
Published Elsevier B.V 2002
Subjects
Band shapes
Excited states
Infrared
Vibrational
Vibrational
Infrared
Excited states
Band shapes
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Summary:This article describes the behaviour of the shapes of the IR bands of coordination compounds on electronic excitation. Broadening on excitation is frequently, but not invariably, observed; any broadening is the result of a subtle interplay of the properties of the vibrational mode, the excited state and the solvent.
ISSN:0010-8545
1873-3840
DOI:10.1016/S0010-8545(01)00471-4