Palladium-catalysed substitution reactions of geminal allylic diacetates

The Pd(0)-catalysed substitution of allylic 1,1-diacetates by both carbon and oxygen nucleophiles is described. The products isolated resulted from either single or double substitution reactions. Graphic

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Bibliographic Details
Published inTetrahedron letters Vol. 39; no. 29; pp. 5281 - 5284
Main Authors van Heerden, Fanie R., Huyser, Johan J., Bradley, D., Williams, G., Holzapfel, Cedric W.
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 16.07.1998
Elsevier
Subjects
allylation
Chemistry
Chemistry, Organic
Palladium and compounds
Physical Sciences
Science & Technology
substitution
Palladium and compounds
allylation
substitution
palladium and compounds
ALKYLATION
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Summary:The Pd(0)-catalysed substitution of allylic 1,1-diacetates by both carbon and oxygen nucleophiles is described. The products isolated resulted from either single or double substitution reactions. Graphic
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(98)01000-4